Glamour puss: Pixie Lott oozes sex appeal in low-cut leather dress and big hair at Temperley London show during LFW

PUBLISHED: 09:07, 18 February 2013 | UPDATED: 11:19, 18 February 2013

She’s already been seen at a number of catwalk shows at London Fashion Week, wearing a variety of cute outfits.

But on Sunday Pixie Lott decided to go sexy as she slipped into a slinky leather dress to attend the Temperley London show.

The 22-year-old made sure all eyes were on her in the daring, skintight dress with a zip up the front and her big hair, creating a very glamorous look.

Stealing the show: Pixie Lott wowed in leather at Temperley London on Sunday

The pretty blonde, who often opts for a more preppy style, really vamped it up in the low-cut dress which made the most of her enviable figure.

Falling just above her knees the Mama Do singer had her best assets – her legs- firmly on display.

Going bare legged she accentuated them further with a pair of ankle-strapped, open-toe black stilettos.

Mama Wow: Pixie showed off her enviable figure in the skintight black dress with zip that looked super sexy

Meanwhile her blonde hair had much more volume than usual and in keeping with the bombshell look she wore lashings of black mascara and eyeliner.

Following the show Pixie took to Twitter to express her feelings on the show, she wrote: ‘Beautiful and timeless @TemperleyLondon ❤’

Other guests at the show included American reality star Olivia Palermo who wore a patterned mini dress, showing off her seemingly endless legs.

Overall look: Pixie completed her glamorous look by wearing her hair big and accentuating her eyes with lots of mascara and eye-liner

Caped crusader: Kate Nash stood out wearing a bright red tartan cape while she carried a small black bag which looked like a radio

She teamed the interesting dress with a pair of funky sunglasses as she carried her large fluffy looking coat.

Singer Kate Nash opted for an eye-catching ensemble which consisted of a red tartan cape, beneath which she wore a bright red cape.

It seems Pixie’s blonde Pin-Up look fitted in perfectly with the theme of Temperley show as the collection was an ode to Hitchcock muse Tippi Hedren.

Fashion lovers: Olivia Palermo (L) looked chic on arrival as did model Jacquetta Wheeler (R)

Speaking to Vogue about the collection which featured a notably darker palette than usual,Temperley said: ‘I’m having fun playing with new bases and new builds,

‘And there’s more of an emphasis on layering this season and developing different fabrics.’

‘It’s important that people don’t just see us as occasionwear,’ she continued.

Matchy, matchy: Singer Kate wore red lipstick, red nails and a red anchor necklace

Fashion fan Pixie has already been seen at a number of shows during the three days of London Fashion Week.

As well as being seen cosying up to The Saturdays at the Julian McDonald show she was also seen attending the Rankin show with her model boyfriend Oliver Cheshire.

In between attending shows, Pixie has been hitting the studio working on her new album.