Pop superstar Cheryl, hhe former X Factor beauty left her new man Liam Payne at home as she strutted her stuff while walking into the event.
The star - who split from husband Jean-Bernard last year - appeared to have returned to racy pop roots as she stunned in a daring little black dress and killer thigh-high leather boots.
Booti-ful! Kim may have be one of the main head turners at the bash, but she had a lot of competition on her hands in the form of pop superstar Cheryl
Back to her best! The star - who split from husband Jean-Bernard last year - appeared to have returned to racy pop roots as she stunned in a daring little black dress and killer thigh-high leather boots
Stand out: Cheryl proved she's just as good as any supermodel as she Vogued in the gala dinner - while Kanye enjoyed a drink in the back
Hell for leather! The former X Factor beauty left her new man Liam Payne at home as she strutted her stuff while walking into the event
While Kim and Cheryl were the talking points of the evening, the catwalk queens invited along didn't exactly disappear into the background.
Among the supermodels in attendance was Lara Stone, who certainly turned heads with her very revealing black gown.
The Dutch beauty, 32, may be a mother of one, but she proved she can still flash the flesh as she showed off some serious underboob in the mesh segmented number.
Seriously racy: Among the supermodels in attendance was Lara Stone, who certainly turned heads with her very revealing black gown
Whoa mama! The Dutch beauty, 32, may be a mother of one, but she proved she can still flash the flesh as she showed off some serious underboob in the mesh segmented number
Red-dy to shine: Lara's dress made the most of her sizeable assets and her long legs
Strike a pose! Lara was seen stopping for a picture alongside Lily Donaldson as the great and the good mingled inside
Scarlet woman: Lily wowed in a stunning gem-encrusted red gown as she sashayed into the bash
What a ruby! The supermodel worked the exquisite creation which she had paired with a matching clutch and dash of red lipstick
Moss be a good bash: Keeping with the blonde runway diva theme was Kate Moss, who stunned in a sheer black sequinned gown over a leotard
Cut above: Kate playfully stroked hairdresser Sam McKnight's bald head as she was joined by make-up artist Charlotte Tilbury
Fun time gal: The model looked in high spirits as she playfully showed off her purse
Keeping with the blonde runway diva theme was Kate Moss.
The striking fashion legend looked highly polished as she sported a sheer black sequinned gown over a leotard.
Another platinum icon who arrived in style at the Vogue bash was Claudia Schiffer.
The German beauty - one of the original pack of supermodels - defied her 45 years as she stunned in a ruffled black LBD.
Keeping her long legs on show, albeit in black tights, the star's trademark blonde tresses were in sleek waves for the evening.
She met up with couture queen Erin O'Connor, who looked statuesque in plunging sheer gown patterned with flowers.
Blonde ambition: Another northern European blonde who arrived in style at the Vogue bash was Claudia Schiffer
Amazonians: She met up with couture queen Erin O'Connor, who looked statuesque in plunging sheer gown patterned with flowers
Couture queen: Erin showed off the poses which made her a hugely in-demand model
Three's a crowd: Yasmin Le Bon and pop star husband Simon also attended and stopped to chat to male model David Gandy
Playful pair: The cute couple stunned in bright ensembles before messing around for a snap
It wasn't just the style crowd who turned out to celebrate the fashion bible.
Hollywood actress Demi Moore also made her mark at the event after stunning at the Chelsea Flower Show earlier in the day.
The stunning brunette looked decades younger than her 53 years as she slipped into a slinky black and red sequinned number.
With her trademark long raven looks falling over her shoulder, the star smoldered in the racy number, which featured a high neck and sheer cut-outs.
Gimme Moore! Demi Moore provided some Hollywood glamour in a red and black sequinned dress with sheer panels
Meanwhile, home grown talent Alexa Chung and Daisy Lowe certainly proved their style credentials as they hit the red carpet at the Vogue 100 gala dinner in London on Monday night.
Model and fashionista Alexa looked sensational in a vintage strapless gold dress, which she wore with '80s polka dot tights and heels.
The super-slim star worked the cameras as she strutted her stuff on the red carpet while heading into the event.
She was closely followed by Daisy, who looked spring-ready in a colourful '50s-style frock, which she accessorised with a bright pink clutch and simple strappy heels.
Also a guest at the dinner was Pixie Geldof, who looked sensational in a long silk patterned number boasting a backless design.
She arrived on the arm of her boyfriend George Barnett, and the couple shared a kiss in front of the cameras.
Come on, Vogue! Alexa Chung certainly proved her style credentials as she hit the red carpet at the Vogue 100 gala dinner in London on Monday night
Golden girl: Model and fashionista Alexa looked sensational in a vintage strapless gold dress, which she wore with '80s polka dot tights and heels
Golden touch: The model was keen to show off her retro number as she swirled it around for the cameras
Pretty in pastels: She was closely followed by Daisy, who looked spring-ready in a colourful '50s-style frock, which she accessorised with a bright pink clutch and simple strappy heels
Bright young thing: Daisy rocked the vibrant number, added a dash of red lipstick to her quirky look
The dinner was part of the ongoing celebrations to mark the British version of the fashion bible turning 100 years old.
In February, the supermodels of the world united to mark the opening of the Vogue 100: A Century of Style exhibition at the National Portrait Gallery, a display featuring the finest works shot for the style bible since its launch in 1916.
The exhibition marks the centenary of the British arm of Vogue, which was exported to the UK by American publisher Condé Montrose Nast in 1916.
Glamour: Sir Bob Geldof's daughter Pixie looked sensational in a long silk patterned number boasting a backless design
Beau: She arrived on the arm of her boyfriend George Barnett, who looked dapper in a black suit
Loved up: The pair enjoyed a smooch on the red carpet as they made their way into the dinner
Gal pals together: The trio of fashionistas looked thrilled to be back in each other's company
Lady in red! Georgia May Jagger looked divine in an ankle grazing burgundy dress as she clutched a pretty grey bag
Cute couple: Gemma Chan and Jack Whitehall looked happy together as they posed for pictures in their monochrome outfits
Stunning: Gemma Chan looked fantastic in her elegant black and white lace dress teamed white black sandals and a Burberry bag
Refined style: Actor Damian Lewis looked dapper in a smart suit as he was joined by his wife Helen McCrory on the red carpet
Wonderful in white: Helen McCrory dazzled in a flowing ivory gown embroidered with colourful spring flowers
It is the first of its kind, celebrating the images which have graced the pages of the magazine over the last centry.
The works of Cecil Beaton, Irving Penn, David Bailey, Herb Ritts, Mario Testino and Corinne Day all appeared in the display.
It featured some of British Vogue's most iconic shots, from Princess Diana posing in a tiara for Testino, to 90's grunge-era Kate Moss and even a model standing among the rubble in war-torn London during the Blitz.
Legends: Joan Collins dazzled in gold as she joined modelling icons Marie Helvin and Twiggy at the bash
Blooming lovely! Laura Bailey looked lovely in a cream summer dress with floral trim and white platforms at the party
Stunners: Model Sophie Dahl looked ravishing in a sheer black dress while Laura Carmichael stunned in a simple silver gown and make-up artist Jemma Wesley stunned in a bright orange two piece
Boys' club: Kanye stopped for a photo with Sophie's jazz singer husband Jamie Cullum
Designers: Dapper gents Tom Ford and Giorgio Armani both donned dinner suits for the big evening
Family affair: Ab Fab star Jennifer Saunders mingled with the crowd she usually mocks as she looked chic at the event alongside daughter Freya Edmondson
Other snaps include the Beckhams at the height of their '90s fame, a cocky young Jude Law, late great designer Alexander McQueen and even the future King of England, Price Charles, who was snapped posing with chickens on his country estate.
Speaking about what makes Vogue so iconic, Shulman - who has edited since 1992 - said that the publication was 'very clear about the core values [of fashion] while being open to adaptation and innovation.'
Aimed as a guide for the rich and wealthy to spend their money, the magazine transcended its original boundaries of reporting the latest fashion trends to purchase to become a bench-mark for social events, culture and trends of the day.
Top man: Even London's new mayor Sadiq Khan stepped out for the event, and he and his wife Saadiya were greeted by editor Alexandra
Read more: http://www.dailymail.co.uk/tvshowbiz/article-3605486/Kim-Kar-flashian-Reality-TV-queen-flaunts-famous-figure-revealing-khaki-dress-steals-star-studded-Vogue-100-gala-dinner-London.html#ixzz49Yz0Dlri
Follow us: @MailOnline on Twitter | DailyMail on Facebook
Support disadvantaged children and young people with the @BBCCiN T-shirt here: http://bbc.co.uk/pudsey #cin
